| Abstract |
The synthesis, characterization of trans-[Cr(N2)2(depe)2] (1) is described. 1 and trans-[Cr(N2)2(dmpe)2] (2) catalyze the reduction of N2 to N2H4 and NH3 in THF using SmI2 and H2O or ethylene glycol as proton sources. 2 produces the highest total fixed N for a molecular Cr catalyst to date. |
| Authors |
Charles H. Beasley , Olivia L Duletski  , Ksenia S. Stankevich , Navamoney Arulsamy  , Michael T. Mock
|
| Journal Info |
Royal Society of Chemistry | Dalton Transactions , vol: 53
, iss: 15
, pages: 6496 - 6500
|
| Publication Date |
1/1/2024 |
| ISSN |
1477-9226 |
Type |
article |
| Open Access |
closed
|
| DOI |
https://doi.org/10.1039/d4dt00702f |
| Keywords |
Nitrogen Reduction (Score: 0.519244) , Catalysis (Score: 0.514993) , Nanocatalysts (Score: 0.506265)
|
